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61.
A meso‐scale particle model is presented to simulate the expansion of concrete subjected to alkali‐aggregate reaction (AAR) and to analyze the AAR‐induced degradation of the mechanical properties. It is the first attempt to evaluate the deterioration mechanism due to AAR using the discrete‐element method. A three‐phase meso‐scale model for concrete composed of aggregates, mortar and the interface is established with the combination of a pre‐processing approach and the particle flow code, PFC2D. A homogeneous aggregate expansion approach is applied to model the AAR expansion. Uniaxial compression tests are conducted for the AAR‐affected concrete to examine the effects on the mechanical properties. Two specimens with different aggregate sizes are analyzed to consider the effects of aggregate size on AAR. The results show that the meso‐scale particle model is valid to predict the expansion and the internal micro‐cracking patterns caused by AAR. The two different specimens exhibit similar behavior. The Young's modulus and compressive strength are significantly reduced with the increase of AAR expansion. The shape of the stress–strain curves obtained from the compression tests clearly reflects the influence of internal micro‐cracks: an increased nonlinearity before the peak loading and a more gradual softening for more severely affected specimens. Similar macroscopic failure patterns of the specimens under compression are observed in terms of diagonal macroscopic cracks splitting the specimen into several triangular pieces, whereas localized micro‐cracks forming in slightly affected specimens are different from branching and diffusing cracks in severely affected ones, demonstrating different failure mechanisms. Copyright © 2012 John Wiley & Sons, Ltd.  相似文献   
62.
从1株海绵内生真菌(Alternaria sp.)链格孢菌的发酵液中提取胞外多糖,对其进行Q Sepharose FF离子交换色谱分离纯化,得到2个组分JJY-W和JJY-S。运用各种化学方法及波谱方法对JJY-W和JJY-S的理化性质及结构进行分析,并对多糖清除自由基活性进行了评价。结果表明,JJY-W和JJY-S的分子量分别为1.4KD和1.8KD;JJY-W以半乳糖、葡萄糖为主,含有少量甘露糖,摩尔比为:甘露糖∶葡萄糖∶半乳糖=1∶2.5∶11。JJY-S以甘露糖、葡萄糖为主,含有少量半乳糖,摩尔比为:甘露糖∶葡萄糖∶半乳糖=3∶2∶1。JJY-W总糖含量为46.3%,未检测出糖醛酸,蛋白含量为2%。JJY-S总糖含量为52%,糖醛酸含量为6.1%,蛋白含量为14%。活性分析表明,2种多糖均具有一定的体外抗氧化活性,并随着浓度的增加清除自由基能力均增强,JJY-W清除DPPH自由基的活性要强于JJY-S,而JJY-S清除OH.自由基的活性要强于JJY-W。  相似文献   
63.
李世娜  刘永 《海洋学报》2010,32(10):6882-6888
利用基于密度泛函理论的第一性原理全势线性缀加平面波方法,研究了立方反ReO3结构Cu3N在零温(0 K)零压下的平衡晶格常数、体弹模量及其对压强的一阶导数,计算结果与其他实验及理论结果基本相符. 同时得出Cu3N的弹性常数,Poisson比等,并分析出Cu3N在零温零压下是稳定的. 通过准谐Debye模型计算Cu3N的热力学性质,得到了Cu3N的晶格常数、等压比热容、等容比热  相似文献   
64.
Geologically constrained inversion of gravity and magnetic field data of the Victoria property (located in Sudbury, Canada) was undertaken in order to update the present three‐dimensional geological model. The initial and reference model was constructed based on geological information from over 950 drillholes to constrain the inversion. In addition, downhole density and magnetic susceptibility measured in six holes were statistically analysed to derive lower and upper bounds on the physical properties attributed to the lithological units in the reference model. Constrained inversion of the ground gravity and the airborne magnetic data collected at the Victoria property were performed using GRAV3D and MAG3D, respectively. A neural network was trained to predict lithological units from the physical properties measured in six holes. Then, the trained network was applied on the three‐dimensional distribution of physical properties derived from the inversion models to produce a three‐dimensional litho‐prediction model. Some of the features evident in the lithological model are remnants of the constraints, where the data did not demand a significant change in the model from the initial constraining model (e.g., the thin pair of diabase dykes). However, some important changes away from the initial model are evident; for example, a larger body was predicted for quartz diorite, which may be related to the prospective offset dykes; a new zone was predicted as sulfide, which may represent potential mineralisation; and a geophysical subcategory of metabasalt was identified with high magnetic susceptibility and high density. The litho‐prediction model agrees with the geological expectation for the three‐dimensional structure at Victoria and is consistent with the geophysical data, which results in a more holistic understanding of the subsurface lithology.  相似文献   
65.
与广泛分布于干旱河谷的宽级配砾石土体特征不同,冰碛土广泛分布在青藏高原地区,属粗大颗粒多、粘粒含量少、摩擦阻力大、粘滞阻力小的宽级配砾石土体。在冰川融雪与降雨的共同作用下冰碛土体可失稳并起动泥石流,形成灾害。针对冰碛土体起动泥石流机理研究薄弱的现状,本文选取波密县帕隆藏布流域的支流嘎弄沟一冰碛土堆积坡面,通过模拟降水与冰雪融水起动冰川泥石流实验,比较不同颗粒组成、不同实验条件下的土体起动泥石流特征,分析其起动成因及力学特性,探讨冰碛土体起动泥石流的机理。研究发现冰碛土体失稳起动泥石流是粘滞阻力降低、孔隙水压力升高、拖曳力与渗流侵蚀共同作用的结果,起动过程受粘土颗粒含量和径流类型的影响。当粘粒含量较高时(>3%),土体通过铲蚀与面蚀形成泥石流;粘粒含量中低时(不高于3%),大部分坡面土体主要经掏蚀与坍塌起动泥石流;粘粒含量过低时(<0.32%),土体难以起动泥石流。在降水作用下土体孔隙水压力迅速增加,易造成土体破坏,起动泥石流;而在冰雪融水的作用下,土体孔隙水压力波动幅度不大时,土体同样可能发生失稳破坏起动泥石流。  相似文献   
66.
南堡油田保持中深层泥页岩井壁稳定钻井液研究   总被引:1,自引:0,他引:1  
在南堡油田中深层钻井过程中,东二、东三、沙一段泥页岩的剥落掉块经常造成井壁坍塌掉块、钻具阻卡、电测遇阻等井下复杂情况。分析了中深层泥页岩的理化特性,研究探讨了泥页岩的坍塌机理。在此基础上,提出了选用强封堵抑制型钻井液是有效抑制中深层泥页岩剥落掉块的根本措施。这一研究成果对于在南堡油田中深层开发工程中提高钻速、减少井下复杂情况发生具有重要意义。  相似文献   
67.
The Indonesian Throughflow (ITF) links upper ocean waters of the west Pacific and Indian Ocean, modulates heat and fresh water budgets between these oceans, and in turn plays an important role in global climate change. The climatic phenomena such as the East Asian monsoon and El Niño-Southern Oscillation (ENSO) exert a strong influence on flux, water properties and vertical stratification of the ITF. This work studied sediments of Core SO18462 that was retrieved from the outflow side of the ITF in the Timor Sea in order to investigate response of the ITF to monsoon and ENSO activities since the last glacial. Based on Mg/Ca ratios and oxygen isotopes in shells of planktonic foraminiferal surface and thermocline species, seawater temperatures and salinity of both surface and thermocline waters and vertical thermal gradient of the ITF outflow were reconstructed. Records of Core SO18462 were then compared with those from Core 3cBX that was recovered from the western Pacific warm pool (WPWP). The results displayed that similar surface waters occurred in the Timor Sea and the WPWP during the last glacial. Since ~16 ka, an apparent difference in surface waters between these two regions exists in salinity, indicated by much fresher waters in the Timor Sea than in the WPWP. In contrast, there is little change in difference of sea surface temperatures (SSTs). With regard to thermocline temperature (TT), it increased until ~11.5 ka since the last glacial, and then remained an overall unchanged trend in the WPWP but continuously decreased in the Timor Sea towards the late Holocene. Since ~6 ka, thermocline waters have tended to be close to each other in between the Timor Sea and the WPWP. It is indicated that intensified precipitation due to East Asian monsoon and possible ENSO cold phase significantly freshened surface waters over the Indonesian Seas, impeding the ITF surface flow and in turn having enhanced thermocline flow during the Holocene. Consequently, thermocline water of the ITF outflow was cooling and thermocline was shoaling towards the late Holocene. It is speculated that, in addition to strengthening of East Asian winter monsoon, increasing ENSO events during the late Holocene likely played an important role in influencing thermocline depth of the ITF outflow.  相似文献   
68.
To identify impact factors on the distribution and characters of natural plants community in reclamation area, with survey data from 67 plant quadrats in July 2009, soil properties data from 216 sampling points in April 2009, and TM (30 m) data in 2006, the composition and characteristics of natural plants community in different time of the Fengxian area in the Changjiang (Yangtze) River estuary were analyzed with two-way indicator species analysis (TWINSPAN), multivariate analysis of variance (MANOVA), detrended canonical correspondence analysis (DCCA) and canonical correspondence analysis (CCA). The results show that: 1) The plant communities in the reclaimed area are mainly mesophytes and helophytic-mesophytic transitional communities, showing a gradient distribution trend with the change in reclamation years. Species richness (MA), species diversity (H) and above-ground biomass also increase with the increase of reclamation years. Nevertheless, they appear to decline slightly in the middle and late reclamation period (> 30 years). 2) With the rise in land use levels, the changes in species richness and species diversity tend to increase at first and then decrease; species dominance (D), however, tends to decline; and above-ground biomass increases slightly. 3) The distribution of the plant community is mainly influenced by the following factors: land use levels (R = 0.55, p < 0.05), soil moisture (R = 0.53, p < 0.05), soil salinity (R = 0.43, p < 0.05) and reclamation time (R = 0.40, p < 0.05).  相似文献   
69.
2009-2010年冬季南海东北部中尺度过程观测   总被引:2,自引:1,他引:1  
根据南海北部陆架陆坡海域2009-2010年冬季航次的CTD调查资料,发现西北太平洋水在上层通过吕宋海峡入侵南海,其对南海东北部上层水体温盐性质的影响自东向西呈减弱趋势,影响范围可达114°E附近。入侵过程中受东北部海域反 气旋式涡旋(观测期间,其中心位于20.75°N,118°E附近) 的影响,海水的垂向和水平结构发生了很大变化,特别是涡旋中心区域,上层暖水深厚,混合层和盐度极大值层显著深于周边海域。该暖涡在地转流场、航载ADCP观测海流及卫星高度计资料中均得到了证实。暖涡的存在还显著影响了海水化学要素的空间分布,暖涡引起的海水辐聚将上层溶解氧含量较高的水体向下输运,使次表层的暖涡中心呈现高溶解氧的分布特征。  相似文献   
70.
黄河三角洲粉质土海床临界起动切应力影响因素研究   总被引:1,自引:0,他引:1  
在黄河口潮滩和室内环形土槽模拟新沉积的海床土体,观测固结过程中沉积物临界起动切应力的变化及对应的土体重度、含水率、贯入阻力、剪切强度指标值的变化,分析黄河三角洲粉质类土临界起动切应力的影响因素与变化规律。研究发现:黄河三角洲粉土的临界起动切应力与重度、贯入阻力和抗剪强度之间呈正相关关系,而与含水率呈负相关关系,并且与干密度、抗剪强度之间具有非常好的定量关系。将黄河三角洲粉土临界侵蚀切应力的试验结果与其他学者建立的计算公式进行了比较,发现在固结开始试验与计算结果间的吻合性较好,随着固结时间差异性变大,表现出黄河口粉质土的独特性。  相似文献   
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